SUMAC
GENERALITIES
There are various species
of Sumac, a small tree found in Mediterranean areas. The most
valuable for tanning purpose is the one cultivated in South Europe
called « Rhus Coriaria ». With Chestnut, it is the
only tan of industrialised countries origin.
Rhus
Coraria
The harvest is made in Summer
when the leaves start to be reddish. On one acre, 10,000 trees
can grow, giving 800 Kg of dry leaves.
HISTORY
Sumac is one of the noblest
and most ancient tanning material of the Mediterranean world.
It was used by Egyptian and Greek during Antiquity as a wool dye
and later as a tan extract.
The botanic name of Sumac comes from the Antic Roman tanner called
« Coriarii » in latin language.
Cultivated in the Middle Age by Arabs in Palestine, this extract
has made the glory and wealth of tanners producing genuine Morocco
and Cordovan leather.
Nowadays, Sumac is mainly used by tanneries producing high valuable
furniture and bag items.
COMPOSITION
Sumac belongs to the pyrogallic
family. The leaves contain around 30 % of a tan which is the condensation
of gallic, digallic acid with glucose.
Extraction of Sumacs
tan is very particular compared to other vegetable extracts as
it is very sensitive to heat (decomposition into gallic acid).
It is the reason why only few manufacturers are able to offer
a Sumac extract unaltered by oxidation with a concentration of
tan from 56 to 62 % after spraydrying.
The impurities forwarded are free gallic acid, glucose, greenish
dye (Chlorophyl), inorganic salt. All these compounds give interesting
properties, except salt like iron oxide which has to be stripped
out to avoid patchiness.
PROPERTIES
Compared to all other vegetable
tans except Tara, Sumac has excellent light fastness certainly
due to the strong antioxidation nature of gallic group.
When used alone, yellow-greenish leather is obtained with a very
light weight, smooth grain and unusual softness for a full vegetable
tanning.
These particularities could be of some interest for the technician
who would like to develope special articles with natural extracts.
For example, due to gallic acid group, Sumac gives a slightly
reversible tannage on the surface of the leather. This is an excellent
property comparable to the action of naphtalene based syntans.
By adding Sumac 10-15 prior to the dye, better uniformity,
faster penetration are possible. With most of the black dyes which
are of blue tone, it enhances the jetness because of its own yellowish
shade. Contrary to syntans, we can note that Sumac has no bleaching
effect and it increases the burnishability of leather.
Another advantage is its high affinity with basic dyes allowing
irreversible complex firmly fixed on the grain side, giving good
dry rub fastness on nubuck and suede. By using Sumac with cationic
fatliquor, two way nap effect and high shine appear.
Apart from dyes auxilialy, Sumac could be interesting in
upholstery, automotive and articles which need to be light weight,
thin and soft..
It is commonly used for lining and bookbinding because of its
excellent perspiration and light fastness.
As all vegetable tan, Sumac enhances glazability and because of
glucoside and antioxydation property of gallic acid, it prevents
the grain side from cracking and improves the tear resistance
of vegetable leather after ageing.
COMMERCIAL
BRANDS
RETAN
BLK-M
Ground Sumac, micronized and purified. It gives a strong tea smell
to leather. When used for the production of shrunken and bold
grain, the strong deshydration given by latest action of gallic
acid and absorption by the insoluble parts of the grounded powder
provoke an uniform, flat, shrunken grain on the pelt.
RETAN BLK-M could be used for hard grain Morocco leather and as
a substitute to grounded Tara and Myrobolam when pleasant smell
and high dyeing uniformity are needed.
RETAN
K19
It is the most common in the Market because of its fairly high
tan content - around 58 % - and its versatility. It can be used
with all other vegetable and syntan without special care.
RETAN
BL, liquid
Unaltered Sumac of the best origin. Its medium astringency and
nominal percentage of insoluble make this extract specially recommended
as a dye auxiliary and for the manufacture of thin, soft leather
of high value. RETAN BL is also used for the tannage of reptile
and crocodile.
RETAN
TSK
It is the best Sumac for tanners processing small skins like goat,
sheep with a pure aniline finish. Grain of such skins retanned
with « TSK » remain flat with a mellow touch.
RETAN TSK is also used as dye mordant on leather, textile, nylon
and cotton.