RETAN SFK

 

 

1. PRODUCT IDENTIFICATION

Product Name

RETAN SFK

Supplier

S.C. RAOUL-DUVAL & Cie

7, place Léon-Meyer, B.P. 1414

F-76067 Le Havre Cedex, France

Phone (33) 2 35 19 66 20
Fax (33) 2 35 21 55 08
Urgency phone number (33) 2 35 19 66 20

2. PRODUCT COMPOSITION

Composition Tanning extract based on soluble Quebracho
Equivalence Natural pyrocatechic tannin coming from Quebracho
CAS 89 957 460
EINECS 289 564 9
Dangerous ingredients NONE

 

3. HAZARD IDENTIFICATION

Under normal use conditions, this product is stable. The product is astringent and of bitter taste. May give off SO2 and SO3 under action of extreme heat.

It can provoke respiratory difficulties by inhalation of the powder and gastric and intestinal disorders by ingestion in large quantity.

 

4. FIRST AID MEASURES

Skin contact Wash with water
Eyes contact Wash with plenty of water
Ingestion Drink large amount of liquids and make vomit if person is conscious.
Inhalation Wash mucous membranes. If irritation persists, seek medical advice.

 

5. FIRE PRECAUTIONS/FIRE FIGHTING

All extinguisher types can be used.

In case of fire, the product can give off bitter and irritant fumes, and SO2, SO3, pyrocatechol. Respiratory masks are recommended.

 

6. ACCIDENTAL RELEASE

Workers' protection Wear personal protective clothes
Protection and Cleaning Sweep up, wash residue with water and mix residue with sawdust. Dispose of according to local regulations or incinerate.
Neutralisation In aqueous solution, the product precipitates the metallic salts and specially alumine sulphate.

 

7. HANDLING & STORAGE

Handling Wear respiratory masks to avoid respiring dusts or absorbing by inhalation.
Storage Keep away from air and humidity. The product is slightly hygroscopic and becomes oxidised with air.

Do not use hooks for handling the bags.

8. PERSONAL PROTECTION

Handling Wear personal protective equipment
Hands Rubber or PVC gloves can be advised

 

Follow good hygiene conditions and wear personal protective equipment.

 

9. PHYSICAL & CHEMICAL PROPERTIES

Appearance (colour) pinky beige
Form spraydried powder
Odour characteristic
pH (10% solution at 20°C) 4,5 +- 1,0
Solubility in water soluble
Density 0,45 g/cm3 +-0,05
Decomposition T°C > 250°C
Flash point N/A
Melting point N/A

 

10. STABILITY & REACTIVITY

Under normal use conditions, this product is stable. It precipitates in presence of metallic salts and specially iron ones and gelatine. It is sensitive to oxidising agents. At high temperature, may give off pyrocatechol, SO2 and SO3.

 

11. TOXICOLOGICAL INFORMATION

We have no figure on toxicological values actually.

The mixture is made with sulphited extracts of Quebracho wood.

Analysis on similar tanning extract gives :

LD 50 oral rat : 3,100 mg/Kg

LD 50 skin rat : 7,000 mg/Kg

No disastrous effect, no sensitisation to this product have been reported until today.

As every pulverulent product the powder may provoke respiratory problems by inhalation.

 

12. ECOLOGICAL INFORMATION

Natural product of high molecular weight ; biodegradability is low. The product is very sensitive to metallic salts and is disposed of in waste waters under the form of mud by treatment with alumine sulphate. Although the effects on environment and waters are not disastrous, at the moment we have no figure on ecotoxicity.

 

13. WASTE DISPOSAL

Dispose of according to local regulations.

The product is eliminated of aqueous solutions by precipitation under the form of muds with alumine sulphate (formation of alumine tannate).

Elimination of residue and packing by incineration.

 

14. TRANSPORT INFORMATION

The product is not regulated.

 

15. REGULATORY INFORMATION

Health & Safety Regs.

EC Directives 76-464, 78-318, 80-68, 91-156
EC Directive 93-18 of 5th April 1993

Official French Gazette of 28th March 1993, Decree of 1th October 93 relative to taking off and water consumption as well as to disposals of any type, and specially,

Chapter VI Art. 60 water pollution
Chapter VII Art. 61 environmental evaluation
Chapter VIII Art. 63/64/65 control of effects on environment

 

16. OTHER INFORMATION

This product should be stored, handled and used in accordance with good industrial hygiene practices and in conformity with any legal regulation. The information contained herein is based on the present state of our knowledge and is intended to describe our products from the point of view of safety requirements. It should not, therefore, be construed as guaranteeing specific properties.

 

Material Safety Data Sheet

Edition : 18.07.01

Index : 0

Code : AQUSFK

Document PC.074/A